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61.
In this study we describe measures taken in our laboratory to improve the long-term precision of nitrate and ammonia analysis in seawater using a microflow segmented-flow analyzer. To improve the nitrate reduction efficiency using a flow-through open tube cadmium reactor (OTCR), we compared alternative buffer formulations and regeneration procedures for an OTCR. We improved long-term stability for nitrate with a modified flow scheme and color reagent formulation and for ammonia by isolating samples from the ambient air and purifying the air used for bubble segmentation. We demonstrate the importance of taking into consideration the residual nutrient content of the artificial seawater used for the preparation of calibration standards. We describe how an operating procedure to eliminate errors from that source as well as from the refractive index of the matrix itself can be modified to include the minimization of dynamic refractive index effects resulting from differences between the matrix of the samples, the calibrants, and the wash solution. We compare the data for long-term measurements of certified reference material under two different conditions, using ultrapure water (UPW) and artificial seawater (ASW) for the sampler wash.  相似文献   
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The accurate estimation of hydraulic conductivity is important for many geotechnical engineering applications, as the presence of fluids affects all aspects of soil behaviour, including its strength. Darcy’s law is the key experimental (or phenomenological) equation employed to model ground water flow. Yet, this phenomenological equation can be linked to a more fundamental microscale model of flow through the pore spaces of the porous material. This paper provides an experimental verification of the relationships between Darcy’s law (macroscale) and the Navier–Stokes equations (microscale) for actual complex pore geometries of a granular material. The pore geometries are experimentally obtained through state-of-the-art X-ray computer assisted micro-tomography. From the numerical modelling of the microscale flow based on actual pore geometries, it is possible to quantify and visualize the development of pore-scale fluid preferential flow-paths through the porous material, and to assess the importance of pore connectivity in soil transport properties.  相似文献   
64.
Subsurface ocean temperature indices are developed to identify two distinct types of tropical Pacific warming (El Ni?o) and cooling (La Ni?a) events: the Eastern-Pacific (EP) type and the Central-Pacific (CP) type. Ocean temperature anomalies in the upper 100?m are averaged over the eastern (80°W?C90°W, 5°S?C5°N) and central (160°E?C150°W, 5°S?C5°N) equatorial Pacific to construct the EP and CP subsurface indices, respectively. The analysis is performed for the period of 1958?C2001 using an ocean data assimilation product. It is found that the EP/CP subsurface indices are less correlated and show stronger skewness than the sea surface temperature (SST)-based indices. In addition, while both quasi-biennial (??2?years) and quasi-quadrennial (??4?years) periodicities appear in the SST-based indices for these two types, the subsurface indices are dominated only by the quasi-biennial periodicity for the CP type and by the quasi-quadrennial (??4?years) periodicity for the EP type. Low correlation, high skewness, and single leading periodicity are desirable properties for defining indices to separate the EP and CP types. Using the subsurface indices, major El Ni?o and La Ni?a events identified by the Ni?o-3.4 SST index are classified as the EP or CP types for the analysis period. It is found that most strong El Ni?o events are of the EP type while most strong La Ni?a events are of the CP type. It is also found that strong CP-type La Ni?a events tend to occur after strong EP-type El Ni?o events. The reversed subsequence (i.e., strong EP El Ni?o events follow strong CP La Ni?a events) does not appear to be typical. This study shows that subsurface ocean indices are an effective way to identify the EP and CP types of Pacific El Ni?o and La Ni?a events.  相似文献   
65.
The geotechnical characteristics of Ulleung Basin sediments are explored using depressurized samples obtained at 2100 m water depth and 110 m below the sea floor. Geotechnical index tests, X-ray diffraction, and SEM images were obtained to identify the governing sediment parameters, chemical composition and mineralogy. We use an instrumented multi-sensor oedometer cell to determine the small-strain stiffness, zero-lateral strain compressibility and electromagnetic properties, and a triaxial device to measure shear strength. SEM images show a sediment structure dominated by microfossils, with some clay minerals that include kaolinite, illite, and chlorite. The preponderant presence of microfossils determines the high porosity of these sediments, defines their microstructure, and governs all macroscale properties. The shear wave velocity increases as the vertical effective stress increases; on the other hand, porosity, permittivity, electrical conductivity, and hydraulic conductivity decrease with increasing confinement. All these parameters exhibit a bi-linear response with effective vertical stress due to the crushable nature of microfossils. Well-established empirical correlations used to evaluate engineering parameters do not apply for these diatomaceous sediments which exhibit higher compressibility than anticipated based on correlations with index properties. Settlements will be particularly important if gas production is attempted using depressurization because this approach will cause both hydrate dissociation and increase in effective stress.  相似文献   
66.
We documented the temporal occurrence patterns and habitat use of fish in the Mangyeong River estuary on the western coast of Korea from February to December 2003 based on monthly samples collected with a stow net. A total of 46 fish species were collected during the study period. Chelon haematocheilus, Konosirus punctatus, Neosalanx jordani, Sardinella zunasi, Synechogobius hasta, and Thryssa kammalensis were the predominate species, accounting for 84.4% of the collected fish. We classified the fish as brackish water (BF), coastal migratory (CMF), diadromous (DF), or freshwater (FF) fish. BF such as C. haematocheilus, S. hasta, and Coilia nasus were the most abundant and were collected almost year-round. As water temperatures increased in spring, adult CMF, such as K. punctatus, S. zunasi, T. kammalensis, T. adelae, Johnius grypotus, Miichthys miiuy, and Larimichthys polyactis, entered the estuary. In summer, large numbers of their juvenile offspring were caught, indicating a peak in fish abundance. The juveniles grew in the estuary before moving out to deeper waters for overwintering. Diadromous juveniles, such as those of Anguilla japonica (commonly known as glass eel), were collected in the spring during their upstream migration. FF, such as Carassius cuvieri and Acheilognathus rhombeus, were collected during the rainy season. In terms of the number of species, the number of individuals, and the biomass, the ratio of BF to all other fish type classifications in the Mangyeong Estuary (without a dam) was higher than that in the Geum River estuary (with a dam). The fish assemblage in the Mangyeong Estuary still maintained estuarine characteristics before dike enclosure, providing habitats for BF, nursery grounds for CMF, and migratory pathways for DF.  相似文献   
67.
Physical characterization of core samples recovered from Gulf of Mexico   总被引:2,自引:1,他引:1  
Seventy whole rounds from conventional cores obtained during drilling to 300 mbsf at Atwater Valley and Keathley Canyon in the Gulf of Mexico in April and May 2005 were tested to determine geophysical and geomechanical parameters (liquid and plastic limit, porosity, specific surface, pH, sediment electrical conductivity, P- and S-wave velocities and undrained shear strength). Available data from a pressure core are included as well. Results show that the sediments are high specific surface plastic clays, and exhibit pronounced time-dependent stiffness recovery. Strains during coring disturb specimens, yet, the water content retains the effective stress history and permits gaining stiffness and strength information from conventional cores. Remolding is exacerbated when gas expands upon decompression; the limited pressure core data available show the advantages of preserving the pore fluid pressure during core recovery and testing. Valuable parameters for sediment characterization and engineering analysis are extracted from the data using pre-existing soil models.  相似文献   
68.
On protected mudflats and along sheltered tidal channel margins, wave- and current-generated ripples are frequently observed on surficial and subsurface mud beds, although such bedforms are generally not thought to occur in cohesive sediments. In this paper, examples of such ripple marks in the German Wadden Sea (back-barrier tidal flats of Spiekeroog island) and also along the west coast of Korea (Baeksu tidal flats) are documented and analyzed. The mud ripples are 5–8 cm in spacing and 0.3–0.8 cm in height, and are composed of slightly sandy to virtually pure mud (80–98% mud content). For the Spiekeroog study area, a comparison of in situ particle-size measurements of suspended matter and of dispersed mud collected from the ripples shows that the former consists of low-density flocs which are considerably larger than the constituent grains of the latter. To assess local wave effects, near-bed orbital velocities and orbital diameters were calculated on the basis of standard wave theory using estimated wave parameters at the time of the study (June 2004) as well as wave data recorded nearby within the back-barrier tidal basin. The relationships between grain size, morphometric ripple parameters, and the near-bed orbital diameter show the wave-generated mud ripples to be of the orbital post-vortex type. It is demonstrated that only short-period shoaling (intermediate water depth) waves with periods of 1.5–2.5 s and heights of 0.1–0.5 m are able to generate and maintain such ripples. Corresponding near-bed orbital velocities range from 8–32 cm s–1 and near-bed orbital diameters from 6.25–10 cm. It can be anticipated that increased current shear and turbulence associated with higher and longer waves prevent ripple formation due to the resuspension of settled mud, and the breakdown of suspended flocs and aggregates into smaller particles which then tend to remain in suspension. The most plausible explanation for the formation of the mud ripples is that mud flocs and aggregates deposited from suspension around high-water slack tide under moderate weather conditions initially respond as single (non-cohesive) particles which are hydraulically equivalent to ambient very fine sands. During exposure at low tide, gradual loss of water transforms the rippled mud into increasingly more cohesive mud drapes which are more resistant to erosion. Unless destroyed during high-energy events, the mud ripples may remain intact long enough to become buried and thereby preserved. Indeed, occasional but persistent observations of ripples in sub-Recent to ancient mudrocks document their preservation potential.  相似文献   
69.
A numerical sediment transport model was embedded into a coupled wave-tide-circulation model to quantitatively estimate the suspended sediment fluxes (SSF) and distribution in different areas for the Yellow River derived sediment. The model is validated by comparing model simulated sediment deposition rates with those from observations. Simulated results show that the SSF of the Yellow River across two major sections (the Bohai Strait and the 37° N section) are highest during September and October, whereas for the 32° N section the flux is negligibly small (less than 0.1 kg/s). We demonstrate that the sediment flux is primarily driven by the buoyancy forcing of the Yellow River freshwater discharge and modulated by the wind-driven surface wave and circulation patterns in this region. The SSF across the Bohai Strait is about 30 % of the Yellow River discharge, while across the 37° N section it is 15.8 %. Therefore, about 70 % of the total discharged Yellow River sediments are deposited in the Bohai Sea, 14.1 % in the North Yellow Sea, and 13.9 % in the South Yellow Sea. There are two deposition branches in the Yellow Sea. The primary one is located off the eastern tip of the Shandong Peninsula and extends to the southwest off the coastline, which is consistent with the observed “Ω”-shape deposition pattern. This simulated tongue shape deposition pattern is isolated from the north by the strong resuspension off the eastern tip of Shandong Peninsula. The secondary branch extends to the middle of the South Yellow Sea and has been strengthened by resuspension process. The two deposition branches are separated by the wintertime Yellow Sea Warm Current in the bottom layer.  相似文献   
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